Stop trying to call them. Stop attempting any other contact except to post and mail a 3 day quit or pay notice. If you cannot hand this to the tenant, you must post it on the door and go to the court house and swear out a 'cerificate of service'.
If you do not get paid before the morning of the 4th day...go file immediately for eviction.
You should never wait on late rent.
I do not know your State...check the laws in your state..you may have a different number of days required for the notice.